Science & engineering

Arrhenius rate ratio

Compare rate constants at two absolute temperatures using an activation energy.

Arrhenius rate ratio
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Assuming unchanged pre-exponential factor and activation energy, ln(k₂/k₁)=−Ea/R × (1/T₂−1/T₁). Converts kJ/mol to J/mol and uses R=8.31446261815324 J/(mol·K). Reports the logarithmic ratio even when the ordinary ratio exceeds floating-point range. This compares rate constants, not complete reaction time, conversion or a changed mechanism.

See a worked example

Worked example

A fixed demonstration, separate from the values you enter above.

Activation energy (kJ/mol)
50
First absolute temperature (K)
298.15
Second absolute temperature (K)
308.15

Example result

Natural logarithm of rate ratio
0.654543980936
Rate constant k₂ / k₁
1.92426481583
Base-10 logarithm of rate ratio
0.284264839084